|
In chemistry and atomic physics, an electron shell, or a principal energy level, may be thought of as an orbit followed by electrons around an atom's nucleus. The closest shell to the nucleus is called the " shell" (also called "K shell"), followed by the " shell" (or "L shell"), then the " shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond with the principal quantum numbers (''n'' = 1, 2, 3, 4 ...) or are labeled alphabetically with letters used in the X-ray notation (K, L, M, …). Each shell can contain only a fixed number of electrons: The first shell can hold up to two electrons, the second shell can hold up to eight (2 + 6) electrons, the third shell can hold up to 18 (2 + 6 + 10) and so on. The general formula is that the ''n''th shell can in principle hold up to 2(''n''2) electrons.〔(Re: Why do electron shells have set limits ? ) madsci.org, 17 March 1999, Dan Berger, Faculty Chemistry/Science, Bluffton College〕 Since electrons are electrically attracted to the nucleus, an atom's electrons will generally occupy outer shells only if the more inner shells have already been completely filled by other electrons. However, this is not a strict requirement: atoms may have two or even three incomplete outer shells. (See Madelung rule for more details.) For an explanation of why electrons exist in these shells see electron configuration.〔(Electron Subshells ). Corrosion Source. Retrieved on 1 December 2011.〕 The electrons in the outermost occupied shell (or shells) determine the chemical properties of the atom; it is called the ''valence shell''. Each shell consists of one or more ''subshells'', and each subshell consists of one or more atomic orbitals. ==History== The shell terminology comes from Arnold Sommerfeld's modification of the Bohr model. Sommerfeld retained Bohr's planetary model, but added mildly elliptical orbits (characterized by additional quantum numbers ' and ''m'') to explain the fine spectroscopic structure of some elements.〔Donald Sadoway, ''Introduction to Solid State Chemistry'', (Lecture 5 )〕 The multiple electrons with the same principal quantum number (''n'') had close orbits that formed a "shell" of positive thickness instead of the infinitely thin circular orbit of Bohr's model. The existence of electron shells was first observed experimentally in Charles Barkla's and Henry Moseley's X-ray absorption studies. Barkla labeled them with the letters K, L, M, N, O, P, and Q. The origin of this terminology was alphabetic. A "J" series was also suspected, though later experiments indicated that the K absorption lines are produced by the innermost electrons. These letters were later found to correspond to the ''n'' values 1, 2, 3, etc. They are used in the spectroscopic Siegbahn notation. The physical chemist Gilbert Lewis was responsible for much of the early development of the theory of the participation of valence shell electrons in chemical bonding. Linus Pauling later generalized and extended the theory while applying insights from quantum mechanics. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Electron shell」の詳細全文を読む スポンサード リンク
|